continuation of #109595
pkgconfig was aliased in 2018, however, it remained in
all-packages.nix due to its wide usage. This cleans
up the remaining references to pkgs.pkgsconfig and
moves the entry to aliases.nix.
python3Packages.pkgconfig remained unchanged because
it's the canonical name of the upstream package
on pypi.
It's now the default. /cc #19456
This makes a real build simplification, because in our current
bootstrapping+aliases, `gcc6` attribute is not the default compiler
but a derivation *built by* the default compiler.
nix-exec didn't build before this commit already